The following explains how carbon dioxide levels in the atmosphere have been monitored for the past 50+ years at the Mauna Loa station. When done viewing, click on "Related" and then" A Scientist, His work and a Climate Reckoning" for a more detailed article about Keeling and monitoring the atmosphere.
http://www.nytimes.com/interactive/2010/12/22/science/earth/20101222-carbon/index.html
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